γ 射线辐照对 Cr 掺杂 MgAl2O4 晶体光谱特征的影响

doi:10.3969/j.issn.1007-5461.2023.01.009

量子电子学报 ›› 2023, Vol. 40 ›› Issue (1): 79-84.doi: 10.3969/j.issn.1007-5461.2023.01.009

γ 射线辐照对 Cr 掺杂 MgAl2O4 晶体光谱特征的影响

孙贵花1∗ , 张庆礼1 , 罗建乔1 , 高进云1 , 刘文鹏1 , 李加红1,2 , 陈迎迎1,2

( 1 中国科学院合肥物质科学研究院安徽光学精密机械研究所, 安徽省光子器件与材料重点实验室, 安徽合肥 230031; 2 中国科学技术大学, 安徽合肥 230026 )

收稿日期:2021-04-23 修回日期:2021-07-13 出版日期:2023-01-28 发布日期:2023-01-28
通讯作者: E-mail: ghsun@aiofm.ac.cn E-mail:E-mail: ghsun@aiofm.ac.cn
作者简介:孙贵花 ( 1984 - ), 女, 山东人, 博士, 副研究员, 主要从事晶体生长及性能方面的研究。 E-mail: ghsun@aiofm.ac.cn
基金资助:
先进激光技术安徽省实验室主任基金 (AHL20220ZR04)

Eﬀect of γ-ray irradiation on spectral characteristics of Cr-doped MgAl2O4 crystal

SUN Guihua 1∗ , ZHANG Qingli 1 , LUO Jianqiao 1 , GAO Jinyun 1 , LIU Wenpeng 1 , LI Jiahong 1,2 , CHEN Yingying 1,2

( 1 Anhui Provincial Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China; 2 University of Science and Technology of China, Hefei 230026, China )

Received:2021-04-23 Revised:2021-07-13 Published:2023-01-28 Online:2023-01-28

摘要/Abstract

摘要： 为评估辐照对 Cr:MgAl2O4 晶体光谱特性的影响, 采用辐照剂量为 100 Mrad 的 60Co γ 射线照射抛光后的 Cr: MgAl2O4 晶体样品片, 测量了辐照前后的拉曼光谱、透射光谱和荧光特性, 并对辐照前后光谱变化的原因进行了分析。研究结果表明: 样品的拉曼振动峰值的位置和强度都受到辐照的影响, 但振动峰的数量没有改变; 由于色心的吸收, 辐照后 250∼600 nm 波长范围内的透射率均明显降低; 辐照前后样品的荧光发射峰位一致, 但辐照后荧光强度明显降低, 同时辐照后的荧光寿命显著增加。

关键词: 激光晶体, γ 射线辐照, Cr:MgAl2O4 晶体, 光谱性能

Abstract: In order to evaluate the eﬀect of irradiation on the spectral properties of Cr:MgAl2O4 crystal, Raman spectra, transmittance spectra and ﬂuorescence properties of the polished Cr:MgAl2O4 crystal were measured before and after γ irradiation with a dose of 100 Mrad, and the mechanism of the irradiation eﬀect were analyzed. The results show that the position and intensity of Raman vibration peak are both aﬀected by irradiation, but the number of vibration peaks does not change. And due to the absorption of color center, the transmittance in the wavelength range of 250-600 nm decreases obviouslyafter γ irradiation. The ﬂuorescence emission peaks of the samples after irradiation are consistent with those of before irradiation, while the ﬂuorescence emission intensity decreases signiﬁcantly and the ﬂuorescence lifetime increases signiﬁcantly after irradiation.

Key words: laser crystal, γ irradiation, Cr:MgAl2O4 crystal, spectral properties

中图分类号:

TN244

孙贵花∗, 张庆礼, 罗建乔, 高进云, 刘文鹏, 李加红, 陈迎迎. γ 射线辐照对 Cr 掺杂 MgAl2O4 晶体光谱特征的影响[J]. 量子电子学报, 2023, 40(1): 79-84.

SUN Guihua ∗ , ZHANG Qingli , LUO Jianqiao , GAO Jinyun , LIU Wenpeng , LI Jiahong , , CHEN Yingying , . Eﬀect of γ-ray irradiation on spectral characteristics of Cr-doped MgAl2O4 crystal[J]. Chinese Journal of Quantum Electronics, 2023, 40(1): 79-84.

参考文献

[1] Maiman T H.Stimulated Optical Radiation in Ruby[J].Nature, 1960, 187:493-494
[2] Kubodera K, Noda J.Pure single-mode LiNdP4O12 solid-state laser transmitter for 1.3-μm fiber-optic communications[J].Appl. Optic., 1982, 21:3466-3469
[3] Brancaleon L, Moseley H.Laser and non-laser light sources for photodynamic therapy[J].Lasers Med. Sci., 2002, 17:173-186
[4] Bachmann F.Industrial applications of high power diode lasers in materials processing[J].Appl. Surf. Sci., 2003, 208:125-136
[5] Koopmans B, Malinowski G, Dalla Longa F, et al.Explaining the paradoxical diversity of ultrafast laser-induced demagnetization[J].Nat. Mater., 2010, 9:259-265
[6]White G S, Lee K H, and Crawford J H.Effeets of γ-Irradiation upon the optical behavior of spinel[J].Phys. Stat., 1977, 42 501(a):137-141
[7] Kinoshita C.Radiation-induced microstructural change in ceramic materials[J].J. Nuel. Mater., 1992, 67:191-194
[8] White G S, Lee K H, and Crawford J H.Thermochemical coloration and annealing of spinel and magnesium oxide[J].Appl. Phys. Lett., 1979, 35(1):1-3
[9]Lorincz A, Puma M, James F J, and Crawford J H.Thermally stimulate processes involving defects in γ-and X-irradiation spinel (MgA12O4)[J].J. Appl. Phy., 1982, 53(2):927-932
[10] Sato T, Shirai M, Tanaka K, et al.Strong blue emission from Ti-doped MgAl2O4 crystals[J].J. Lumin., 2005, 114:155-161
[11]Jouini A, Sato H, Yoshikawa A, et al.Ti-doped MgAl2O4 spinel single crystals grown by the micro-pulling-down method for laser application: Growth and strong visible blue emission[J].J. mater. Res., 2006, 21(9):2337-2344
[12] Brik M G, Papan J, Jovanovi? D J, Drami?anin M D.Luminescence of Cr3+ ions in ZnAl2O4 and MgAl2O4 spinels: correlation between experimental spectroscopic studies and crystal field calculations[J].J. Lumin., 2016, 177:145-151
[13] Tomita A, Sato T, Tanaka K, et al.Luminescence channels of manganese-doped spinel[J].J. Lumin., 2004, 109:19-24
[14] Jouini A, Yoshikawa A, Guyot Y, et al.Potential candidate for new tunable solid-state laser between 1 and 2 μm: Ni2+-doped MgAl2O4 spinel grown by the micro-pulling-down method[J].Opt. Mater., 2007, 30:47-49
[15] Yumashev K V, Denisov I A, Posnov N N, et al.Nonlinear absorption properties of Co2+:MgAl2O4 crystal[J].Appl. Phys. B, 2000, 70:179-184
[16] Sun G H, Zhang Q L, Luo J Q, et al.Bulk Crystal Growth of Cr-doped MgAl2O4 spinel by Czochralski method and properties characterization [J].Mater. Chem. Phys., 2018, 204:277-281
[17] O' Horo M P, Frisillo A L, and White W B.Lattice vibrations of MgAl2O4 spinel[J].J. Phys. Chem. Solids, 1973, 34:23-28
[18] Van Minh N, Yang I-S.A Raman study of cation-disorder transition temperature of natural MgAl2O4 spinel [J].Vib. Spectrosc., 2004, 35:93-96
[19]Schmocker V, Boesch H R, Waldner F.A direct determination of cation disorder in spinel MgA12O4 by ESR[J].Phys. Lett., 1972, 40(3):237-238
[20] White G S, Jones R V, and Crawford J H.Optical spectra of MgA12O4 crystals exposed to ionizing radiation[J].J. Appl. Phys., 1982, 53:265-270
[21]Luo C X, Xia H P, Yu C, et al.Effect of γ -ray irradiation and O2 annealing on spectral properties of Bi:CdWO4 single crystal[J].Spectroscopy and Spectral Analysis, 2012, 32(6):1476-1479
[22] Matkovskii A, Sugakc D, Melnyk S, et al.Colour centers in doped Gd3Ga5O12 and Y3Al5O12 laser crystals[J].J. Alloy. Compd., 2000, 300-301:395-397

γ 射线辐照对 Cr 掺杂 MgAl2O4 晶体光谱特征的影响

Eﬀect of γ-ray irradiation on spectral characteristics of Cr-doped MgAl2O4 crystal

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