基于SOF-FTIR的机场VOCs污染排放监测分析

量子电子学报

基于SOF-FTIR的机场VOCs污染排放监测分析

韩昕1,2，李相贤1*，高闽光1，魏秀丽1，童晶晶1，李胜1，叶树彬1,2，李妍1,2

（1.中国科学院安徽光学精密机械研究所，安徽合肥 230031； 2.中国科学技术大学，安徽合肥，230026）

出版日期:2019-01-28 发布日期:2019-01-17
通讯作者: lixx@aiofm.ac.cn
作者简介:韩昕（1990-），女，安徽阜阳，博士，主要从事红外光谱分析方面的研究工作。Email:xhan@aiofm.ac.cn
基金资助:
Support by the National High Technology Research and Development Program of China (国家重点研发计划项目,2017YFC0209902), Young Scientists Fund of the National Natural Science Foundation of China(国家自然科学基金青年科学基金, 41605015), Director fund of Anhui Institute of Optics and Fine Mechanics(安徽光学精密机械研究所所长基金, AGHH201502)， Natural Science Foundation of Anhui Provincial（安徽省自然科学基金,1708085MD94）

Monitoring and Analyzing VOCs Pollution Emissions in Airport with SOF-FTIR

HAN Xin1,2 ,LI Xiang-xian1 ,GAO Min-guang1 ,TONG Jing-jing 1,,WEI Xiu-li1, ,LI Sheng1,YE Shu-bin1,2 ,LI Yan1,2

(1.Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences，Anhui Hefei 230031； 2 .China University of Science and Technology, Anhui Hefei 230026)

Published:2019-01-28 Online:2019-01-17

摘要/Abstract

摘要： 为了研究机场排放对环境大气的影响，在2014年12月10日到16日，采用掩日通量遥测傅里叶红外技术（SOF-FTIR）对某国际机场的乙烯(C2H4)，己烷(C6H14)和一氧化碳(CO)排放进行了研究。分析了三种组份的特征浓度值及其变化趋势，结果表明三者的特征浓度值变化趋势上具有高度相关性；机场乙烯的平均柱浓度为13.18ppmm，己烷的平均柱浓度为97.82ppmm，一氧化碳的平均柱浓度为3065.56ppmm。通过结合国际民航组织(ICAO, International Civil Aviation Organization)发布的测量数据，得到某国际机场乙烯和己烷的排放量分别达到碳氢化合物排放总量的3.32%和66.96%。文章结果表明，掩日通量遥测FTIR技术与ICAO的数据具有较好的一致性，为评估飞机排放提供数据支撑。

关键词: SOF-FTIR, 飞机尾气, 特征浓度, VOCs

Abstract: To study the impact of emissions at an airport on local air quality, a measurement campaign at the Beijing Capital International Airport was performed from 10 December 2014 to 16 December 2014. Measurements of, CO,C2H4 and C6H14 were conducted with solar occulation flux -fourier transform infrared spectrometer (SOF-FTIR) system to determine real in-use emission indices of aircraft . The characteristic concentration values of three target gas were analyzed .The results shows that there was a high correlation between them and the average column concentration of ethylene, hexane and Carbon monoxide in the airport are 13.18ppmm 97.82ppmm , 3065.56ppmm, separately. By combining the measurement data released by ICAO, it can be concluded that the emissions of ethylene and hexane at an international airport have reached the levels of total hydrocarbon emissions 3.32% and 66.96%, respectively. The results show that the SOF-FTIR technology has good consistency with ICAO data and provides technical support for the assessment of aircraft emissions.

韩昕1,2，李相贤1*，高闽光1，魏秀丽1，童晶晶1，李胜1，叶树彬1,2，李妍1,2. 基于SOF-FTIR的机场VOCs污染排放监测分析[J]. 量子电子学报.

HAN Xin1,2,LI Xiang-xian1,GAO Min-guang1,TONG Jing-jing 1,,WEI Xiu-li1,,LI Sheng1,YE Shu-bin1,2,LI Yan1,2. Monitoring and Analyzing VOCs Pollution Emissions in Airport with SOF-FTIR[J]. Chinese Journal of Quantum Electronics.

参考文献

[1] Zhang Y H, Shao K H, Tang X Y, et al. The study of urban photochemical smog pollution in China[J], Journal of Peking University (Natural Science), 1998, 34(2-3): 260-268. [2] Chameides W, Walker G．A photochemical theory of tropospheric ozone[J]． Journal of Geophysical Research, 1973, 36: 8751–8760. [3] Wu R R, Bo Y, Li J, et al．Method to establish the emission inventory of anthropogenic volatile organic compounds in China and its application in the period 2008-2012 [J]. Atmospheric Environment, 2016, 127:244–254． [4] Xu J, Ding G A, Yan P, et al. Componential Characteristics and Sources Identification of PM2.5 in Beijing[J], JOURNAL of Applied Meteorological Science, 2006(18):645-652. [5] Cheng C Y，Yin X B. Source, Composition, Formation and Hazard of PM2.5 in Haze[J]. Journal of University (大学学报),2014,29(5):1-6. [6] 2013年民航行业发展统计公报[EB/OL].http://www.caac.gov.cn/. [7] Airbus GMF booklet2014-203[EB/OL]. http://www.airbus.com/company/market/forecast/. [8] Federal Aviation Administration Office of Environment and Energy. Aviation & Emissions:A Primer[R]. Washington:FAA,2010. [9] Herndon C, Rogers T, Dunlea E, et al. Hydrocarbon emissions from in-use commercial aircraft during airport operations [J]. Environmental Science & Technology,2006,40 (14):4406-13. [10] M. Mazaheri, Johnson R, Morawska L. An inventory of particle and gaseous emissions from large aircraft thrust engine operations at an airport[J]. Atmospheric Environment, 2011, 45(20):3500-3507. [11] David L, David W, Piers M. Aviation and global climate change in the 21st century[J]. Atmospheric Environment ,2009,43(22):3520-3537. [12] Nicole Pauly Hyslop. Impaired visibility: the air pollution people see[J]. Atmospheric Environment, 2009 , 43 (1) :182-195 . [13] Augusto S, Alessandra M. Corrosion on cultural heritage buildings in Italy: a role for ozone?[J]. Environmental Pollution, 2009,157 (5) :1513-1520. [14] Sovde A, Gauss M, Isaksen I. Aircraft pollution-a futuristic view[J].Atmospheric Chemistry and Physics.2003,37:3621-3632. [15] Intergovernmental Panel on Climate Change. Aircraft emissions[R], IPCC, 2008. [16] Kurniawan J, Khardi S. Comparison of methodologies estimating emissions of aircraft pollutants, environmental impact assessment around airports[J]. Environmental Impact Assessment Review, 2011,31(3):240-252. [17] Bruce E, Gao C, Donald R. Hydrocarbon emission from a modern commercial airliner[J]. Atmospheric Environment,2006,40(19):3601-3612. [18] Enis T, Usanmaz O, Rosen A. Empirical model assessment of commercial aircraft emissions according to flight phases[J]. International Journal of Energy & Environmental Engineering,2013,4(1):1-12. [19] Heland J, Schäfer K. Determination of major combustion products in aircraft exhausts by FTIR emission spectroscopy[J]. Atmospheric Environment, 1998,32(97):3067–3072. [20] Klaus S, Carsten J, Peter S. Aircraft emission measurements by remote sensing methodologies at airports[J]. Atmospheric Environment, 2003,37 (37) :5261-5271. [21] International Civil Aviation Organization. International Standards and Recommended Practices, Environmental Protection Annex 16, Volume II Aircraft Engine Emissions,2nd Edition[R]. Montréal: ICAO,2008. [22] Liu Z M, Liu W Q, Gao M G, et al. Study of the retrieval algorithm of emission gas spatio-temporal distribution of pollution source using the infrared Solar Occultation Flux (SOF) method[J]. Acta Physica Sinica(物理学报),2008,59(8):5397-5405.