J4 ›› 2018, Vol. 35 ›› Issue (2): 129-135.

• 光谱 •    下一篇

405 nm飞秒强激光场中H2的碎裂研究

郭玮,常志强,李月华   

  1. 1南华大学电气工程学院,湖南 衡阳 421001; 2中国科学院大连化学物理研究所分子反应动力学国家重点实验室,辽宁 大连 116023
  • 收稿日期:2016-11-04 修回日期:2017-01-09 出版日期:2018-03-28 发布日期:2018-03-30
  • 通讯作者: 郭 玮(1981-),女,博士,副教授,主要从事强激光与物质相互作用方面的研究。E-mail: vella99@163.com
  • 基金资助:
    Supported by National Natural Science Foundation of China(国家自然科学基金, 11447020), Natural Science Foundation of Hunan Province(湖南省自然科学基金, 2015JJ3104), Research Foundation of Education Bureau of Hunan province (湖南省教育厅科研基金15B204)

Fragmentation of H2 in 405 nm intense femtosecond laser field

  1. 1 School of Electrical Engineering, University of South China, Hengyang 421001, China; 2 State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Received:2016-11-04 Revised:2017-01-09 Published:2018-03-28 Online:2018-03-30

摘要: 使用速度成像法测得了405 nm飞秒激光脉冲下H+的动能分布和角分布。讨论了解离通道 、 的反应路径,前者产生于经由 交叉的直接一光子路径,后者产生于 的库仑爆炸。 到 的电离起始于键软化,各通道的相对峰高说明 的解离和电离是竞争的。低场强加强 的解离,高场强支持 的电离。

关键词: 量子光学;反应路径;速度映像成像;光缀饰态

Abstract: The kinetic energy and angular distributions of H+ as a function of 405 nm femtosecond laser intensity are experimentally measured by using velocity map imaging technique. The reaction pathways of dissociation channels, and , are discussed. The former is due to the direct one-photon pathway via the crossing, and the latter stems from Coulomb explosion of . Ionization of to starts from bond softening. The relative yield of fragment peaks indicates that dissociation and ionization of are competitive. The lower laser intensities emphasize the dissociation of , and the higher laser intensities favor the ionization of .

Key words: quantum optics; reaction pathways; velocity map imaging; light-dressed states

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