郑州市PM2.5中无机离子浓度变化特征

量子电子学报 ›› 2019, Vol. 36 ›› Issue (4): 495-499.

郑州市PM2.5中无机离子浓度变化特征

魏秀丽¹,高闽光²,童晶晶²

中国科学院安徽光学精密机械研究所，中国科学院环境光学与技术重点实验室, 安徽合肥 230031

收稿日期:2018-01-29 修回日期:2019-05-21 出版日期:2019-07-28 发布日期:2019-07-11
通讯作者: 魏秀丽
作者简介:魏秀丽(1978- )，女，河南安阳人，硕士，副研究员，主要从事气溶胶化学物理方面的研究。
基金资助:
Supported by National Natural Science Foundation of China (国家自然科学基金, 41375027)

Characterization of Water-Soluble Species of PM2.5 in Zhengzhou

Key Laboratory of Environment Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China

Received:2018-01-29 Revised:2019-05-21 Published:2019-07-28 Online:2019-07-11
Contact: xlwei@aiofm.ac.cn

摘要/Abstract

摘要： 大气气溶胶PM2.5是形成大气灰霾的主要因素，在中国大部分城市已成为首要污染物。2014年春节前夕对郑州市进行了为期一周的大气颗粒物PM2.5样品采集，利用偏最小二乘(PLS)多元变量定量分析模型，分析了郑州市SO42-、NO3-和NH4+三种水溶性离子的衰减全反射傅里叶变换红外光谱(ATR- FTIR)，并与离子色谱（IC）分析结果进行了对比。分析了郑州市春节前夕SO42-、NO3-和NH4+的污染特征和趋势，初步判定了气溶胶的污染来源。

关键词: 偏最小二乘, 衰减全反射傅里叶变换红外光谱, 水溶性离子, 定量分析

Abstract: The atmospheric aerosol PM2.5 is the main factor in the formation of atmospheric haze, and it’s the chief pollutant in most cities in China. Atmospheric particulate PM2.5 sample collection for almost one week before the eve of the 2014 Spring Festival in Zhengzhou is carried out. By using the partial least squares (PLS) multivariate quantitative analysis model, attenuated total reflection Fourier transformed infrared spectroscopy（ATR-FTIR）of the water-soluble ions SO42-, NO3- and NH4+ in Zhengzhou are analyzed, and the results are compared with those of ion chromatography(IC). The pollution characteristics and trend of SO42-, NO3-and NH4+ before the eve of the 2014 Spring Festival in Zhengzhou are analyzed, and the pollution sources of aerosol are preliminarily determined.

Key words: partial least squares, attenuated total reflection Fourier transformed infrared spectroscopy, water-soluble ions, quantitative analysis

魏秀丽高闽光童晶晶. 郑州市PM2.5中无机离子浓度变化特征[J]. 量子电子学报, 2019, 36(4): 495-499.

参考文献

[1]. U.S Environmental Protection Agency Office of Research and Development. Clean Air Research Multi-Year Plan 2008-2012[M]. United States：Research Triangle Park, 2008. [2] Giorgi F, Bi X, Qian Y. Direct radiative forcing and regional climatic effects of anthropogenic aerosols over east asia: A regional coupled climate-chemistry/aerosol model study[J]. Journal of Geophysical Research, 2002, 107 (1320): AAC7/1-AAC7/18. [3] Fan Shu. Comparative Researches on PM2.5 and PAHs compositions between urban and suburban nanjing(南京市区与郊区气溶胶奥PM2.5元素及多环芳烃污染特征的对比研究)[D]. Nanjing: Doctorial Dissertation of Nanjing University of Information Science & Teehnology, 2006(in Chinese). [4] Yang Xia, Cao nji, Shen Zhenxing, et al. Variations of water-soluble ions in PM2．5 at Xi'an between summer and winter [J]. Environmental Chemistry（环境化学），2012, 31(8): 1179-1187(in Chinese). [5] Lv Wenying， Xu Haijuan， Wang Xinming. Major inorganic water-soluble ions in fine particles collected in autumn in urban guangzhou[J]. Environmental Science and Technology， 2010, 33(1): 98-101. [6] Zhang Qiuchen，Zhu Bin，Su Jifeng，et al. Characteristics of aerosol water-soluble inorganic ions in three types air-pollution incidents of nanjing city[J]. Environmental Science(环境科学)，2012, 33(6): 1944-1951 (in Chinese). [7] Tsai J, Owega S, Evans G, et al. Chemical composition and source apportionment of Toronto summertime urban fine aerosol[J]. Journal of Radioanalytical and Nuclear Chemistry, 2004, 259(1): 193-197. [8] Chen Y J, Zheng M, Edgerton E S, et al. PM2.5 source apportionment in the southeastern U.S.: Spatial and seasonal variations during 2001-2005[J]. Journal of Geophysical Research, 2012, 117: D08304. [9] Yu Xuechun. Determination and Characterization of Water-Soluble Species of PM2.5 in Beijing(北京PM2.5水溶性物种污染特征及来源解析)[D].Beijing: Doctorial Dissertation of Tsinghua University, 2004(in Chinese). [10] Xu Honghui. Study on the Characteristics of Mass Concentration and Inorganic Components and the Sources of Aerosol in Beijing and Its Surrounding Area (北京及周边地区大气气溶胶的质量浓度和无机组分的特征及其来源研究) [D]. Beijing: Doctorial Dissertation of Institute of Atmospheric Physics, Chinese Academy of Sciences, 2007(in Chinese). [11]Tan Jihua. The Preliminary Study of the Charcateristice of Aerosols During Haze and Its Effect on Visibility in Guangzhou（广州灰霾期间气溶胶物化特性及其对能见度影响的初步研究）[D]. Guangdong: Doctorial Dissertation of Guangzhou Institute of Geochmistry, Chinese Academy of Sciences，2007(in Chinese). [12] Liu Na, Wei Xiuli, Gao Minguang, et al. A quantitative analysis method of water-soluble inorganic ions with ATR-FTIR spectroscopt[J]. Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2015, 35(12): 3364-3368(in Chinese). [13] Hu Min, He Liangyan, Zhang Yuanhang, et al. Seasonal variation of ionic species in fine particles at Qingdao, China[J]. Atmospheric Environment, 2002, 36: 5853-5859.