光学多通池的研制及应用

doi:10.3969/j.issn.1007-5461.2021.05.006

量子电子学报 ›› 2021, Vol. 38 ›› Issue (5): 617-632.doi: 10.3969/j.issn.1007-5461.2021.05.006

• “激光光谱新技术与应用”专辑 • 上一篇下一篇

光学多通池的研制及应用

方波1,2, 赵卫雄1∗, 杨娜娜1,2, 王春晖1,3, 周昊1,2, 张为俊1,3

1 中国科学院合肥物质科学研究院安徽光学精密机械研究所大气物理化学研究室, 安徽合肥 230031; 2 中国科学技术大学, 安徽合肥 230026; 3 中国科学技术大学环境科学与光电技术学院, 安徽合肥 230026

收稿日期:2021-04-30 修回日期:2021-06-08 出版日期:2021-09-28 发布日期:2021-09-28
通讯作者: E-mail: wjzhang@aiofm.ac.cn E-mail:wjzhang@aiofm.ac.cn
作者简介:方波 ( 1990 - ), 安徽合肥人, 博士生, 主要从事激光光谱技术及应用方面的研究。 E-mail: fangbo@aiofm.ac.cn
基金资助:
Supported by National Natural Science Foundation of China (国家自然科学基金, 41805104, 41627810, 41875151, 42022051), the Youth Innovation Promotion Association CAS (中国科学院青年创新促进会, Y202089)

Development and application of optical multi-pass cells

FANG Bo1,2, ZHAO Weixiong1∗, YANG Na’na1,2, WANG Chunhui1,3, ZHOU Hao1,2, ZHANG Weijun1,3

1 Laboratory of Atmospheric Physico-Chemistry, Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China; 2 University of Science and Technology of China, Hefei 230026, China; 3 School of Environmental Science and Optoelectronic Technology, University of Science and Technology of China, Hefei 230026, China

Received:2021-04-30 Revised:2021-06-08 Published:2021-09-28 Online:2021-09-28

摘要/Abstract

摘要： 光学多通池具有结构简单、光路对准容易、光谱通用性高、鲁棒性好及成本低等优势，是增加吸收光程最有效的手段之一, 可以显著提高吸收光谱的探测灵敏度。简要总结了不同类型光学多通池的基本原理, 重点介绍了中国科学院安徽光学精密机械研究所张为俊研究员团队使用光线追迹研制的 200 m光程像散镜池、 59.7 m 光程 Herriott 池、大于 200 m 光程密集光斑型球面镜池以及带有便携稳定调节机构的 Chernin 池，详述了这些多通池的研制方法及其在激光吸收光谱探测中的应用。

关键词: 光谱学, 吸收光谱, 光学多通池, 吸收光程

Abstract: Due to the advantages of simple structure, easy alignment, high spectral versatility, good robustness and low cost, optical multi-pass cell is one of the most effective means to increase the optical path length and can significantly improve the detection sensitivity of absorption spectroscopy. The basic principles of different types of optical multi-pass cells are summarized firstly. Then a series of optical multi-pass cells developed by Prof. Weijun Zhang′s group of Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences by using ray tracing, including an astigmatic mirror cell with 200 m optical path length, a Herriott cell with 59.7 m optical path length, a dense spot pattern spherical mirror cell with an optical path longer than 200 m and a Chernin cell with portable stabilization adjustment mechanism, are introduced in detail, especially their design methods and applications in laser absorption spectroscopy.

Key words: spectroscopy, absorption spectroscopy, optical multi-pass cells, absorption path length

中图分类号:

0439

方波, 赵卫雄∗, 杨娜娜, 王春晖, 周昊, 张为俊, . 光学多通池的研制及应用[J]. 量子电子学报, 2021, 38(5): 617-632.

FANG Bo, ZHAO Weixiong∗, YANG Na’na, WANG Chunhui, ZHOU Hao, ZHANG Weijun, . Development and application of optical multi-pass cells[J]. Chinese Journal of Quantum Electronics, 2021, 38(5): 617-632.

参考文献

[1] Chen W, Yi H, Wu T, et al. Photonic sensing of reactive atmospheric species [M]. Hoboken: John Wiley & Sons Ltd, Publication, 2017.
[2] Schemshad J, Aminossadati S M, Kizil M S. A review of developments in near infrared methane detection based on tunable diode laser [J]. Sensors and Actuators B: Chemical, 2012, 171(172): 77-92.
[3] Hodgkinson J, Tatam R. Optical gas sensing: a review [J]. Measurement Science and Technology, 2013, 24(1): 012004.
[4] Kan R, Liu W, Zhang Y, et al. Absorption measurements of ambient methane with tunable diode laser [J]. Acta Physica Sinica, 2005, 54(4): 1927-1930.
阚瑞峰, 刘文清, 张玉钧, 等. 可调谐二极管吸收光谱法测量环境空气中的甲烷含量 [J]. 物理学报, 2005, 54(4): 1927-1930.
[5] Graf M, Emmenegger L, Tuzson B. Compact, circular, and optically stable multipass cell for mobile laser absorption spectroscopy [J]. Optics Letters, 2018, 43(11): 2434-2437.
[6] Manninen A, Tuzson B, Looser H, et al. Versatile multipass cell for laser spectroscopic trace gas analysis [J]. Applied Physics B, 2012, 109: 461-466.
[7] Tuzson B, Mangold M, Looser H, et al. Compact multipass optical cell for laser spectroscopy [J]. Optics Letters, 2013, 38(3): 257-259.
[8] Mangold M, Tuzson B, Hundt M, et al. Circular paraboloid reflection cell for laser spectroscopic trace gas analysis [J]. Journal of the Optical Society of America A, 2016, 33(5): 913-918.
[9] Tang Y, Liu W, Kan R, et al. Measurements of NO and CO inShanghai urban atmosphere by suing quantum cascade lasers [J]. Optics Express, 2011, 19(21): 20224-20232.
[10] Fried A, Henry B, Wert B, et al. Laboratory, ground-based, and airborne tunable diode laser systems: performance characteristics and applications in atmospheric studies [J]. Applied Physics B, 1998, 67: 317-330.
[11] Wert B P, Fried A, Rauenbuehler S, et al. Design and performance of a tunable diode laser absorption spectrometer for airborne formaldehyde measurements [J]. Journal of Geophysical Research, 2003, 108(D12): 4350.
[12] Stepanov E V, Zyrianov P V, Miliaev V A. Single-breath NO detection with tunable diode lasers for pulmonary disease diagnosis [J]. Proceedings of SPIE, 1999, 3829: 103-109.
[13] Namjou K, Roller C B, Reich T E, et al. Determination of exhaled nitric oxide distributions in a diverse sample population using tunable diode laser absorption spectroscopy [J]. Applied Physics B, 2006, 85: 427-435.
[14] K?hring M, Huang S, Jahjah M, et al. QCL-based TDLAS sensor for detection of NO toward emission measurements from ovarian cancer cells [J]. Applied Physics B, 2014, 117: 445-451.
[15] Tarsitano C G, Webster C R. Multilaser Herriott cell for planetary tunable laser spectrometers [J]. Applied Optics, 2007, 46(28): 6923-6935.
[16] Webster C R, Mahaffy P R. Determing the local abundance of Martian methane and its’ 13C/12C and D/H isotopic ratios for comparison with related gas and soil analysis on the 2011 Mars Science Laboratory (MSL) mission [J]. Planetary and Space Science, 2011, 59: 271-283.
[17] Mahaffy P R, Webster C R, Cabane M, et al. The sample analysis at Mars investigation an d instrument suite [J]. Space Science Reviews, 2012, 170: 401-478.
[18] Webster C R, Mahaffy P R, Atreya S K, et al. Mars methane detection and variability at gale crater [J]. Science, 2014, 1261713.
[19] Zhang L, Wang F, Yu L, et al. The research for trace ammonia escape monitoring system based on tunable diode laser absorption spectroscopy [J]. Spectroscopy and Spectral Analysis, 2015, 35(6): 1639-1642.
张立芳, 王飞, 俞李斌, 等. 基于可调谐激光吸收光谱技术的脱硝过程中微量逃逸氨气检测实验研究 [J]. 光谱学与光谱分析, 2015，35(6): 1639-1642.
[20] Hui A O, Fradet M, Okumura M, et al. Temperature dependence study of the kinetics and product yields of the HO2+CH3C(O)O2 reaction by direction of OH and HO2 radicals using 2f-IR wavelength modulation spectroscopy [J]. The Journal of Physical Chemistry A, 2019, 123: 3655-3671.
[21] White J. Long optical paths of large aperture [J]. Journal of the Optical Society of America A, 1942, 32: 285-288.
[22] Herriott D, Kogelnik H, Kompfner R. Off-axis paths in spherical mirror interferometers [J]. Applied Optics, 1964, 3(4): 523-526.
[23] McManus J B, Kebabian P L, Zahniser M S. Astigmatic mirror multipass absorption cells for long-path-length spectroscopy [J]. Applied Optics, 1995, 34(18): 3336-3348.
[24] So S, Thomazy D. Novel spherical mirror multipass cells with improved spot pattern density for gas sensing [J]. Conference on Laser and Electro-Optics, 2012, CW3B.6.
[25] Chernin S M, Barskaya E G. Optical multipass matrix systems [J]. Applied Optics, 1991, 30(1): 51-58.
[26] Tuzson B, Graf M, Ravelid J, et al. A compact QCL spectrometer for mobile, high-precision methane sensing aboard drone [J]. Atmospheric Measurement Techniques, 2020, 13: 4715-4726.
[27] Zhou M, Yang Z, Sun L, et al. Acetylene sensing system based on wavelength modulation spectroscopy using a triple-row circular multi-pass cell [J]. Optics Express, 2020, 28(8): 11573-11582.
[28] Cui R, Dong L, Wu H, et al. Three-dimensional printed miniature fiber-coupled multipass cells with dense spot patterns for ppb-level methane detection using a near-IR diode laser [J]. Analytical chemistry, 2020, 92: 13034-13041.
[29] Feng S, Qiu X, Guo G, et al. Palm-Sized laser spectrometer with high robustness and sensitivity for trace gas detection using a novel double-layer toroidal cell [J]. Analytical Chemistry, 2021, 93: 4552-4558.
[30] Webster C R, Flesch G J, Briggs R M, et al. Herriott cell spot imaging increases the performance of tunable laser spectrometers [J]. Applied Optics, 2021, 60(7): 1958-1965.
[31] McManus J B. Paraxial matrix description of astigmatic and cylindrical mirror resonators with twisted axes for laser spectroscopy [J]. Applied Optics, 2007, 46(4): 472-482.
[32] Cui R, Wu H, Li S, et al. Calculation model of dense spot pattern multi-pass cells based on a spherical mirror aberration [J]. Optics Letters, 2019, 44(5): 1108-1111.
[33] Cui R, Dong L, Wu H, et al. Generalized optical design of two-spherical-mirror multi-pass cells with dense multi-circle spot patterns [J]. Applied Physics Letters, 2020, 116:091103.
[34] Chernin S M. Promising version of the three-objective multipass matrix system [J]. Optics Express, 2002, 10(2): 104-107.
[35] Silver J A. Simple dense-pattern optical multipass cells [J]. Applied Optics, 2005, 44(31): 6545-6556.
[36] Wei N, Fang B, Zhao W, et al. Time-resolved laser-flash photolysis Faraday rotation spectrometer: a new tool for total OH reactivity measurement and free radical kinetics research [J]. Analytical Chemistry, 2020, 92: 4334-4339.
[37] Wei N, Zhao W, Fang B, et al. Kinetic studies of reaction between OH radical and alkanes [J]. Chinese Journal of Analytical Chemistry, 2020, 48(8): 1050-1057.
韦娜娜, 赵卫雄, 方波, 等. OH自由基与烷烃反应动力学研究 [J]. 分析化学, 2020, 48(8): 1050-1057.
[38] Wang L, Deng L, Li B, et al. Low-pressure OH radicals reactor generated by dielectric barrier discharge from water vapor [J]. Physics of Plasmas, 2020, 27: 060701.
[39] McManus J B, Zahniser M S, Nelson D. Dual quantum cascade laser trace gas instrument with astigmatic Herriott cell at high pass number [J]. Applied Optics, 2010, 50(4): A74-A85.
[40] Fang B, Yang N, Zhao W, et al. Improved spherical mirror multipass-cell-based interband cascade laser spectrometer for detecting ambient formaldehyde at parts per trillion by volume levels [J]. Applied Optics, 2019, 58(32): 8743-8750.
[41] Glowacki D R, Goddard A, Seakins P W. Design and performance of a throughput-matched, zero-geometric-loss, modified three objective multipasss matrix system for FTIR spectrometry [J]. Applied Optics, 2007, 46(32): 7872-7883.
[42] Glowacki D R, Goddard A, Hemavibool K, et al. Design of and initial results from a Highly Instruments Reactor for Atmospheric Chemistry (HIRAC)[J]. Atmospheric Chemistry and Physics, 2007, 7: 5371-2390.
[43] Tchana F K, Willaert F, Landsheere X, et al. A new, low temperature long-pass cell for mid-infrared to terahertz spectroscopy and sysnchrotron radiation use [J]. Review of Scientific Instruments, 2013, 84: 093101.
[44] Yang X, Zhao W, Tao L, et al. Measurement of volatile organic compounds in the smog chamber using a Chernin multipass cell [J]. Acta Physica Sinica, 2010, 59(7): 5154-5162.
杨西斌, 赵卫雄, 陶玲, 等. 一种新型光学多通池系统应用于烟雾箱内挥发性有机化合物探测 [J]. 物理学报, 2010, 59(7): 5154-5162.
[45] Cheng Y, Zhao W, Hu C, et al. Experimental study of the photochemical reaction in the smog chamber using a Chernin multipass cell [J]. Acta Optica Sinica, 2013, 33(5): 0830001.
陈跃, 赵卫雄, 胡长进, 等. Chernin型多通池用于烟雾箱光化学反应过程的实验研究 [J]. 光学学报, 2013, 33(5): 0830001.
[46] Zhao W, Fang B, Lin X, et al. Superconducting-magnet-based Faraday rotation spectrometer for real time in situ measurement of OH radicals at 106 molecule/cm3 level in an atmospheric simulation chamber [J]. Analytical Chemistry, 2018, 90: 3958-3964.
[47] Fang Bo, Yang N, Wang C, et al. Detection of Nitric Oxide with Faraday rotation spectroscopy at 5.33 μm [J]. Chinese Journal of Chemical Physics, 2020, 33(1): 37-42.
[48] Cuisset A, Hindle F, Mouret G, et al. Terahertz rotational spectroscopy of greenhouse gases using long interaction path-lengths [J]. Applied Sciences, 2021, 11: 1229.
[49] Luo P. Long-wave mid-infrared time-resolved dual-comb spectroscopy of short-lived intermediates [J]. Optics Letters, 2020, 45(24): 6791-6794.
[50] Luo P, Horng E. Simultaneous determination of transient free radicals and reaction kinetics by high-resolution time-resolved dual-comb spectroscopy [J]. Communications Chemistry, 2020, 3: 95.

光学多通池的研制及应用

Development and application of optical multi-pass cells

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