Tm,Ho:GdScO3晶体光谱参数计算

doi:10.3969/j.issn.1007-5461.2025.03.013

量子电子学报 ›› 2025, Vol. 42 ›› Issue (3): 414-424.doi: 10.3969/j.issn.1007-5461.2025.03.013

Tm,Ho:GdScO3晶体光谱参数计算

张俊蕊 1,2,3, 张庆礼 2,3*, 孙贵华 2,3, 李加红 2,3,4, 王小飞 2,3, 窦仁勤 2,3

1 中国科学技术大学环境科学与光电技术学院, 安徽合肥 230026; 2 中国科学院合肥物质科学研究院安徽光学精密机械研究所, 光子器件与材料安徽省重点实验室, 安徽合肥 230031; 3 先进激光技术安徽省实验室, 安徽合肥 230037; 4 中国科学技术大学研究生院科学岛分院, 安徽合肥 230031

收稿日期:2023-05-15 修回日期:2023-05-17 出版日期:2025-05-28 发布日期:2025-05-28
通讯作者: E-mail: zql@aiofm.ac.cn E-mail:E-mail: zql@aiofm.ac.cn
作者简介:张俊蕊 ( 1997 - ), 女, 山东德州人, 研究生, 主要从事稀土激光晶体方面的研究。E-mail: zjr217026@mail.ustc.edu.cn
基金资助:
国家自然科学基金 (51172236, 51802307), 国家重点研发计划 (2022YFB3605700), 先进激光技术安徽省实验室开放研究基金 (AHL20220ZR04, AHL2021KF07), 安徽省科技重大专项 (202203a05020002)

Calculation of spectral parameters of Tm,Ho:GdScO3 crystal

ZHANG Junrui 1,2,3 , ZHANG Qingli 2,3*, Sun Guihua 2,3 , Li Jiahong 2,3,4 , Wang Xiaofei 2,3 , Dou Renqin 2,3

1 College of Environmental Science and Optoelectronic Technology, University of Science and Technology of China, Hefei 230026, China; 2 Anhui Provincial Key Laboratory of Photonics Devices and Materials, Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China; 3 Advanced Laser Technology Laboratory of Anhui Province, Hefei 230037, China; 4 Science Island Branch of Graduate School, University of Science and Technology of China, Hefei 230031, China

Received:2023-05-15 Revised:2023-05-17 Published:2025-05-28 Online:2025-05-28
Supported by:

摘要/Abstract

摘要： 采用提拉法生长了Tm,Ho:GdScO3高质量单晶, 在室温下测量了晶体(100)、(010)与(001)面的透过光谱, 计算了晶体的吸收系数与吸收截面, 以掺杂离子浓度N与吸收振子强度f的乘积为拟合量, 拟合了Tm3＋、Ho3＋共掺杂时的跃迁强度参量Ωt , 并计算自发辐射跃迁几率、辐射寿命及荧光分支比等光谱参数。研究结果表明Tm,Ho:GdScO3 晶体的发光性能良好。本光谱参数计算结果对其激光输出性能的研究提供了数据参考。

关键词: 激光技术, Tm,Ho:GdScO3晶体, 光谱性能, Judd-Ofelt理论

Abstract: High quality single crystals of Tm,Ho:GdScO3 were grown using the Czochralski method. The transmittance spectra of (100), (010) and (001) planes of the crystal were measured at room temperature, and the absorption coefficient and absorption cross-section of the crystal were calculated. The transition intensity parameters Ωt for Tm3+ and Ho3+ co-doped crystal were fitted using the product of dopant concentration N and absorption oscillator intensity f was fitted as a parameter, and the spectral parameters such as spontaneous radiation transition probability, radiative lifetime and fluorescence branching ratio were also calculated. The results show that, the Tm, Ho: GdScO3 crystal has good luminescence performance, and the calculated spectral parameters provide data reference for the study of its laser output performance.

Key words: laser technique, Tm,Ho:GdScO3 crystal, spectral property, Judd-Ofelt theory

中图分类号:

O433.4
TN244

张俊蕊, 张庆礼, 孙贵华, 李加红, 王小飞, 窦仁勤, . Tm,Ho:GdScO3晶体光谱参数计算[J]. 量子电子学报, 2025, 42(3): 414-424.

ZHANG Junrui , , ZHANG Qingli , Sun Guihua , , Li Jiahong , , Wang Xiaofei , , Dou Renqin , . Calculation of spectral parameters of Tm,Ho:GdScO3 crystal[J]. Chinese Journal of Quantum Electronics, 2025, 42(3): 414-424.

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Tm,Ho:GdScO3晶体光谱参数计算

Calculation of spectral parameters of Tm,Ho:GdScO3 crystal

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