Real-time detection of the genus Rosa L. using LIBS technology

doi:10.3969/j.issn.1007-5461.2022.04.003

Abstract

Abstract: Rosa rugosa Thunb., Rosa sp. and Rosa chinensis Jacq. all belong to the genus Rosa L. The three kinds of flowers are similar in appearance and easily confused. The genus Rosa L. has important ornamental value and medicinal value, so it is of great significance to quickly identify the genus Rosa L. Laser induced breakdown spectroscopy (LIBS) is used for in situ detection of the main elements in the three flowers in this work. In addition, CN can also be recognized in the spectrum of the genus Rosa L, so the CN in the spectrum is simulated by using LIFBASE, and the vibration temperature and rotation temperature of CN are calculated. Then the parameters obtained can be regarded as experimental parameters. By comparing and analyzing the laser induced breakdown spectra of the three different kinds of flowers, the characteristic spectral lines with significant difference in intensity are selected as variables to predict flower genus, and combined with the general regression neural network (GRNN), the prediction accuracy could reach 93.3%.

Key words: spectroscopy, detection of the genus Rosa L., laserinduced breakdown spectroscopy, general regression neural network

CLC Number:

O433.4
TN249

YU Wei, ZHOU Zhuoyan, SUN Zhongmou, ZHANG Xinglong, LIU Yuzhu, . Real-time detection of the genus Rosa L. using LIBS technology[J]. Chinese Journal of Quantum Electronics, 2022, 39(4): 494-501.

References

[1] Zhang Y, Jiang Y, Zhu W. Resources of rosa in China and its prospect of landscaping application[J]. Seed, 2009, 28(08): 68-70(in Chinese).
章银柯, 江燕, 朱炜. 我国蔷薇属植物资源及其园林应用前景[J]. 种子, 2009, 28(08): 68-70.
[2] Ghendov-Mosanu A, Cristea E, Patras A, et al. Rose Hips, a Valuable Source of Antioxidants to Improve Gingerbread Characteristics[J]. Molecules, 2020, 25(23).
[3] Kos A, Cu B. Rosa canina waste seed extract-mediated synthesis of silver nanoparticles and the evaluation of its antimutagenic action in Salmonella typhimurium[J]. Materials Chemistry and Physics, 2021, 266: 124537.
[4] Jodaki K, Abdi K, Mousavi M-S, et al. Effect of rosa damascene aromatherapy on anxiety and sleep quality in cardiac patients: A randomized controlled trial[J]. Complementary Therapies in Clinical Practice, 2021, 42.
[5] Karami A. Correlation between Anthocyanin and Essential Oil Content of Damask rose (Rosa damascena Mill.)[J]. Journal of Medicinal Plants and By-Products, 2012.
[6] Qiu X, Zhang H , Li S, et al. Relative relationships analysis of rose germplasm in Yunnan based on SSR markers[J]. Acta Botanica Boreali-Occidentalia Sinica, 2009, 29(09): 1764-1771.
邱显钦, 张颢, 李树发,等. 基于SSR分子标记分析云南月季种质资源亲缘关系(英文)[J]. 西北植物学报, 2009, 29(09): 1764-1771.
[7] Ma Y, Chen J. Pollen morphology of some Rosa species and cultivars[J]. Bulletin of Botanical Research, 1991(03): 69-73+75-76(in Chinese).
马燕, 陈俊愉. 一些蔷薇属植物的花粉形态研究[J]. 植物研究, 1991(03): 69-73+75-76.
[8] Zeng N, Zhang J, Chang zhao, et al. Micromorphological characteristics of leaf epidemis and systematic significance of Rosa L． from China[J]. Guihaia, 2017, 37(02): 169-185(in Chinese).
曾妮, 张建茹, 常朝阳. 中国蔷薇属植物叶表皮微形态特征及其系统学意义[J]. 广西植物, 2017, 37(02): 169-185.
[9] Wen X, Deng X . The Extraction of Genomic DNA from Five Species of Rosa[J]. Seed, 2002(06): 18-21(in Chinese).
文晓鹏, 邓秀新. 五种蔷薇属植物基因组DNA的提取及鉴定[J]. 种子, 2002(06): 18-21.
[10] Yin W, Liu Y, Zhang Q, et al. Online in situ detection of multiple elements and analysis of heavy metals in the incense smoke and ash[J]. Optical Engineering, 2020, 59(2).
[11] Zaytsev S M, Krylov I N, Popov A M, et al. Accuracy enhancement of a multivariate calibration for lead determination in soils by laser induced breakdown spectroscopy[J]. Spectrochimica Acta Part B-Atomic Spectroscopy, 2018, 140: 65-72.
[12] Lu X, Liu Y, Zhou Y, et al. Real-time in situ source tracing of human exhalation and different burning smoke indoors[J]. Spectrochimica Acta Part B-Atomic Spectroscopy, 2020, 170.
[13] Zhang Q, Liu Y, Yin W, et al. The in situ detection of smoking in public area by laser-induced breakdown spectroscopy[J]. Chemosphere, 2020, 242.
[14] Qu Y, Zhang Q, Liu Y, et al. Quantitative analysis of Mn and composition detection in mosquito-repellent incense ash with laser-induced breakdown spectroscopy[J]. Laser Physics, 2019, 29(8).
[15] Yao M, Rao G, Huang L, et al. Simultaneous analysis of Cr and Pb in contaminated pork by laser-induced breakdown spectroscopy[J]. Applied Optics, 2017, 56(29): 8148-8153.
[16] Luo W, Zhao X, Lv S, et al. Measurements of egg shell plasma parameters using laser-induced breakdown spectroscopy[J]. Pramana-Journal of Physics, 2015, 85(1): 105-114.
[17] Zhang Q, Liu Y, Yin W, et al. The online detection of carbon isotopes by laser-induced breakdown spectroscopy[J]. Journal of Analytical Atomic Spectrometry, 2020, 35(2): 341-346.
[18] Xu C, Fan S, Xu Z, et al. Investigation of detection of cadmium in rice leaves based on laser-induced breakdown spectrscopy[J]. Chinese Journal of Quantum Electronics, 2020, 37(03): 363-369(in Chinese).
徐聪, 范爽, 徐琢频, 等. 基于激光诱导击穿光谱检测水稻叶片镉的研究[J]. 量子电子学报, 2020, 37(03): 363-369.
[19] Specht D F. A general regression neural network[J]. IEEE transactions on neural networks, 1991, 2(6): 568-76.