掺WO3对碲酸盐玻璃热稳定性改善和Er3+/Yb3+
掺杂碲钨酸盐玻璃光谱性能的研究

doi:10.3969/j.issn.1007-5461.2024.02.020

量子电子学报 ›› 2024, Vol. 41 ›› Issue (2): 378-387.doi: 10.3969/j.issn.1007-5461.2024.02.020

掺WO3对碲酸盐玻璃热稳定性改善和Er3+/Yb3+ 掺杂碲钨酸盐玻璃光谱性能的研究

陈安民 1,2,3, 马飞云 2, 崔令江 2, 张鹏 1,2, 王传杰 1,2*

( 1 威海长和光导科技有限公司威海市光纤预制棒工程技术研究中心, 山东威海 264200; 2 哈尔滨工业大学(威海)材料科学与工程学院, 山东威海 264209; 3 宏安集团有限公司技术部, 山东威海 264200 )

收稿日期:2022-06-29 修回日期:2022-07-21 出版日期:2024-03-28 发布日期:2024-03-28
通讯作者: E-mail: cjwang@hitwh.edu.cn E-mail:E-mail: cjwang@hitwh.edu.cn
作者简介:陈安民 ( 1993 - ), 山东威海人, 研究生, 主要从事光纤制备方面的研究。E-mail: 2131712152@qq.com
基金资助:
国家自然科学基金 (51875126)

Thermal stability of WO3 doped tellurite glass and spectral properties of Er3+/Yb3+ doped tellurium⁃tungstate glass

CHEN Anmin 1,2,3, MA Feiyun 2, CUI Lingjiang 2, ZHANG Peng 1,2, WANG Chuanjie 1,2*

( 1 Weihai Optical Fiber Preform Engineering Research Center, Weihai Changhe Optical Technology Co. Ltd., Weihai 264200, China; 2 School of Materials Science and Engineering, Harbin Institute of Technology at Weihai, Weihai 264209, China; 3 Department of Technology, Hongan Group Co. Ltd., Weihai 264200, China )

Received:2022-06-29 Revised:2022-07-21 Published:2024-03-28 Online:2024-03-28

摘要/Abstract

摘要： 为得到热稳定性能良好且高强度发光的碲酸盐玻璃，通过在TeO2-ZnO-Na2O 系统中掺入WO3，以提高玻璃的抗析晶和热稳定性能。研究结果表明，碲酸盐玻璃的ΔT 从不掺WO3的110 ℃增加到了WO3含量为20 mol%时的 142 ℃。在热稳定性研究的基础上，进一步分别研究了单掺Er3+和Er3+/Yb3+共掺的碲钨酸盐玻璃的光谱性质。研究结果表明，在Er3+/Yb3+共掺条件下， Er3+/Yb3+之间的能量传递提高了Er3+离子对980 nm 泵浦光的吸收效率，增强了 1.5 μm 波段发光强度，最终得到了具有高强度1.5 μm 波段发光的Er3+/Yb3+共掺碲钨酸盐玻璃，初步证明共掺方式是实现1.5 μm 波段高强度发光的有效方法。

关键词: 光通信, 碲钨酸盐玻璃, 光谱性能, 能量传递, 热稳定性

Abstract: In order to obtain the tellurite glass with good thermal stability and high-intensity luminescence, WO3 is doped into the TeO2-ZnO-Na2O system to improve the anti-devitrification and thermal stability of the glass. The results show that the ΔT of the tellurite glass increases from 110 °C without WO3 to 142 °C with WO3 content of 20 mol%. On the basis of thermal stability study of tellurite glass, the spectral properties of single-doped Er3+ and Er3+/Yb3+ co-doped tellurium tungstate glasses are further studied. The research results show that under the co-doping conditions of Er3+/Yb3+ , the energy transfer between Er3+/Yb3+ improves the absorption efficiency of Er3+ ions for 980 nm pump light, and the luminescence intensity in the 1.5 μm band is enhanced. Finally, Er3+/Yb3+ co-doped tellurium- tungstic glass with high-intensity 1.5 μm band emission is obtained, indicating that the co-doping of Er3+/Yb3+ is an effective method to achieve high-intensity luminescence in the 1.5 μm band.

Key words: optical communication, tellurium-tungstate glass, spectral property, energy transfer, thermal stability

中图分类号:

TQ171

陈安民 , 马飞云 , 崔令江 , 张鹏 , 王传杰 , . 掺WO3对碲酸盐玻璃热稳定性改善和Er3+/Yb3+ 掺杂碲钨酸盐玻璃光谱性能的研究[J]. 量子电子学报, 2024, 41(2): 378-387.

CHEN Anmin , MA Feiyun , CUI Lingjiang , ZHANG Peng , WANG Chuanjie , . Thermal stability of WO3 doped tellurite glass and spectral properties of Er3+/Yb3+ doped tellurium⁃tungstate glass[J]. Chinese Journal of Quantum Electronics, 2024, 41(2): 378-387.

参考文献

[1]. Zhu Y R, Shen X J, Su X, et al. Concentration dependent structural, thermal and luminescence properties in Er3+/Tm3+ doped tellurite glasses[J]. Journal of Non-Crystalline Solids, 2019, 507: 19-29.
[2]. Langar A, Bouzidi C, Elhouichet H, et al. Er-Yb codoped phosphate glasses with improved gain characteristics for an efficient 1.55 μm broadband optical amplifiers[J]. Journal of Luminescence, 2014, 148: 249-255.
[3]. Wang Jinhang. Preparation and Properties of Er3+/Yb3+ Co-doped Superphosphate/Phosphosilicate Glass [D]. Beijing: Master Dissertation of Beijing University of Technology, 2020: 1-3(in Chinese).
王锦航. Er3+/Yb3+共掺超磷酸盐/磷硅酸盐玻璃的制备及其性能研究[D]. 北京: 北京工业大学硕士论文, 2020: 1-3.
[4]. Luo Juping, He You. Analysis on the development of artillery 1.5x μm safety laser rangefinder[J]. Infrared and Laser Engineering, 2008, 37: 242-244(in Chinese).
罗举平, 贺有. 开发炮兵1.5x μm安全型激光测距机浅析[J]. 红外与激光工程, 2008, 37: 242-244.
[5]. Dan H K, Ty N M, Nga V H, et al. Broadband flat near-infrared emission and energy transfer of Pr3+-Er3+-Yb3+ tri-doped niobate tellurite glasses[J]. Journal of Non-Crystalline Solids, 2020, 549: 120335.
[6]. Ding J L, Li C Y, Zhu L Q, et al. Pr3+/Tm3+/Er3+ tri-doped tellurite glass with ultra-broadband luminescence in the optical communication band[J]. Ceramics International, 2022, 48(6): 8779-8782.
[7]. Hou G N, Cao L J, Zhang C M, et al. Improvement of ultra-broadband near-infrared emission in Nd3+-Er3+-Pr3+ tri-doped tellurite glasses[J]. Optical Materials, 2021, 111: 110547.
[8]. Shen S, Naftaly M, Jha A. Tungsten-tellurite-a host glass for broadband EDFA[J]. Optics Communications, 2002, 205(1): 101-105.
[9]. Wu L B, Huang B, Yang F J, et al. Enhanced 1.53 μm band fluorescence in Er3+/Ce3+ codoped tellurite glasses containing Ag NPs[J]. Optical Materials, 2015, 43: 42-48.
[10]. Pandey A, Som S, Kumar V, et al. Enhanced upconversion and temperature sensing study of Er3+-Yb3+ codoped tungsten-tellurite glass[J]. Sensors and Actuators B: Chemical, 2014, 202: 1305-1312.
[11]. Zhang Y, Xiao Z, Lei H, et al. Er3+/Yb3+ co-doped tellurite glasses for optical fiber thermometry upon UV and NIR excitations[J]. Journal of Luminescence, 2019, 212: 61-68.
[12]. El-Mallawany R, Hager I Z, Mahfouz H, et al. Physical and mechanical investigations for bismuth tungsten tellurite glasses[J]. Journal of Alloys and Compounds, 2021, 883: 160802.
[13]. Yuan Jian. Rare earth doped tellurite glass fiber in 2.0 μm band and its spectral and laser experiments [D]. Guangzhou: Doctorial Dissertation of South China University of Technology, 2015: 26-29(in Chinese).
袁健. 2.0 μm波段稀土掺杂碲酸盐玻璃光纤及其光谱和激光实验研究[D]. 广州: 华南理工大学, 2015: 26-29.
[14]. Yuan J, Yang Q, Chen D D, et al. Compositional effect of WO3, MoO3, and P2O5 on Raman spectroscopy of tellurite glass for broadband and high gain Raman amplifier[J]. Journal of Applied Physics, 2012, 111(10): 103511.
[15]. Zhang Y, Xiao Z, Lei H, et al. Er3+/Yb3+ co-doped tellurite glasses for optical fiber thermometry upon UV and NIR excitations[J]. Journal of Luminescence, 2019, 212: 61-68.
[16]. Zhang Y, Lei H, Li G N, et al. Yb3+/Er3+ co-doped transparent tellurite glass-ceramic for enhanced upconversion luminescence[J]. Optical Materials, 2020, 99: 109552.
[17]. Tabanli S, Eryurek G. Optical investigation of Er3+ and Er3+/Yb3+ doped zinc-tellurite glass for solid-state lighting and optical thermometry[J]. Sensors and Actuators A: Physical, 2019, 285: 448-455.

掺WO3对碲酸盐玻璃热稳定性改善和Er3+/Yb3+ 掺杂碲钨酸盐玻璃光谱性能的研究

Thermal stability of WO3 doped tellurite glass and spectral properties of Er3+/Yb3+ doped tellurium⁃tungstate glass

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