锌的激光诱导击穿光谱与等离子体温度研究

doi:10.3969/j.issn.1007-5461.2024.04.003

量子电子学报 ›› 2024, Vol. 41 ›› Issue (4): 587-594.doi: 10.3969/j.issn.1007-5461.2024.04.003

锌的激光诱导击穿光谱与等离子体温度研究

张兴龙1, 张启航1, 刘玉柱1,2,3*

( 1 南京信息工程大学江苏省大气海洋光电探测重点实验室, 江苏南京 210044; 2 南京信息工程大学江苏省大气环境与装备技术协同创新中心, 江苏南京 210044; 3 南京信息工程大学江苏省气象光子学与光电探测国际合作联合实验室, 江苏南京 210044 )

收稿日期:2022-06-01 修回日期:2022-06-30 出版日期:2024-07-28 发布日期:2024-07-28
通讯作者: E-mail: yuzhu.liu@gmail.com E-mail:E-mail: yuzhu.liu@gmail.com
作者简介:张兴龙 ( 1996 - ), 江苏淮安人, 研究生, 主要从事激光光谱方面的研究。E-mail: 20201217016@nuist.edu.cn
基金资助:
国家自然科学基金 (62375136)

Investigation of laser⁃induced breakdown spectroscopy and plasma temperature of zinc

ZHANG Xinglong1 , ZHANG Qihang1 , LIU Yuzhu1,2,3*

( 1 Jiangsu Key Laboratory for Optoelectronic Detection of Atmosphere and Ocean, Nanjing University of Information Science & Technology, Nanjing 210044, China; 2 Jiangsu Collaborative Innovation Center of Atmosphere Environment and Equipment Technology, Nanjing University of Information Science & Technology, Nanjing 210044, China; 3 Jiangsu International Joint Laboratory on Meteorological Photonics and Optoelectronic Detection, Nanjing University of Information Science & Technology, Nanjing 210044, China )

Received:2022-06-01 Revised:2022-06-30 Published:2024-07-28 Online:2024-07-28

摘要/Abstract

摘要： 金属锌的探测工作对于诸多领域有着重要意义。本研究采用激光诱导击穿光谱技术对锌进行了检测分析, 标记出锌在200~895 nm波段内的31条特征谱线。并且在不同激光能量下进行了多次探测, 发现激光能量对于锌谱线的相对强度影响显著。同时计算了不同激光能量下的等离子体温度, 发现等离子体温度随着激光能量的增加而逐渐升高。此外, 研究了离子线与原子线强度比和等离子体温度的关系, 结果表明, 锌的离子线与原子线强度比和等离子体温度之间呈正相关趋势。

关键词: 光谱学, 等离子体温度, 激光诱导击穿光谱, 光谱分析

Abstract: The detection of metallic zinc (Zn) is of great significance in many fields. In this study, the laser-induced breakdown spectroscopy technique is used to detect Zn, and 31 characteristic spectral lines of Zn in the region of 200-895 nm are identified. Moreover, several detections are carried out under different laser energy, and it is found that laser energy has a great influence on the relative intensity of Zn spectral lines. At the same time, the plasma temperature under different laser energy is calculated, and the results indicate that the plasma temperature increases gradually with the increase of laser energy. In addition, the relationship between the ratio of ion line intensity to atomic line intensity and plasma temperature is investigated, and the results show that there is a positive correlation between the ratio of ion line intensity to atomic line intensity and plasma temperature of Zn.

Key words: spectroscopy, plasma temperature, laser-induced breakdown spectroscopy, spectral analysis

中图分类号:

O433.4

张兴龙, 张启航, 刘玉柱, . 锌的激光诱导击穿光谱与等离子体温度研究[J]. 量子电子学报, 2024, 41(4): 587-594.

ZHANG Xinglong , ZHANG Qihang , LIU Yuzhu, . Investigation of laser⁃induced breakdown spectroscopy and plasma temperature of zinc[J]. Chinese Journal of Quantum Electronics, 2024, 41(4): 587-594.

参考文献

[1] Liang G, Mo F, Wang D, et al. Commencing mild Ag-Zn batteries with long-term stability and
ultra-flat voltage platform[J]. Energy Storage Materials, 2019, 25(3).
[2] Shen X, Cao Z, Zhang J, et al. In-situ loading of ZnO nanoparticles on carbon felt as novel
binder-free flexible anode for high performance Lithium-ion batteries[J]. Materials Letters, 2018,
229(OCT.15):93-97.
[3]Gao Z Y, Zhang L C, Chang J L, et al. ZnCo2O4-reduced graphene oxide composite with
balanced capacitive performance in asymmetric supercapacitors[J]. Applied Surface Science: A
Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of
Materials, 2018, 442(Jun.1):138-147.
[4] Wang Y, Liu Z, Lu X, et al. Facile synthesis of high antistatic mica-titania@graphene composite
pearlescent pigment at room temperature[J]. Dyes & Pigments, 2017, 145:436-443.
[5] Chu Y L, Young S J, Dai H R, et al. Improved pH-Sensing Characteristics by Pt Nanoparticle-
Decorated ZnO Nanostructures[J]. ECS Journal of Solid State Science and Technology, 2021,
10(6):067001 (9pp).
[6] Xie Z, Meng L, Feng X, et al. Identification of heavy metal-contaminated Tegillarca granosa
using laser-induced breakdown spectroscopy and linear regression for classification[J]. Plasma
Science and Technology, 2020, 22(8).
[7] Yao S C, Zhang L F, Zhu Y M, et al. Evaluation of heavy metal element detection in municipal
solid waste incineration fly ash based on LIBS sensor[J]. Waste Management, 2020, 102:492-498.
[8] Fang L, Zhao N J, Ma M J, et al. Detection of heavy metals in water samples by laser-induced
breakdown spectroscopy combined with annular groove graphite fakes [J]. Plasma Science &
Technology, 2019, 21: 034002.
[9] Ji G, Ye P, Shi Y, et al. Laser-Induced Breakdown Spectroscopy for Rapid Discrimination of
Heavy-Metal-Contaminated Seafood Tegillarca granosa[J]. Sensors, 2017, 17(11):2655.
[10] Cama-Moncunill R , Casado-Gavalda M P , Cama-Moncunill X , et al. Quantification of
trace metals in infant formula premixes using laser-induced breakdown spectroscopy[J].
Spectrochimica Acta Part B Atomic Spectroscopy, 2017, 135:6-14.
[11] J Bocková, Tian Y, Yin H, et al. Determination of Metal Elements in Wine Using Laser-
Induced Breakdown Spectroscopy (LIBS)[J]. Applied Spectroscopy, 2017, 71(8):3702817708337.
[12] Alsharnoubi J, Nassef Y, Fahmy R F, et al. Using LIBS as a diagnostic tool in pediatrics betathalassemia[
J]. Lasers in Medical Science, 2021, 36(5).
[13] Noll R, Fricke-Begemann C, Connemann S, et al. LIBS analyses for industrial applications –
an overview of developments from 2014 to 2018[J]. Journal of Analytical Atomic Spectrometry,
2018, 33(6):945-956.
[14] Chen X, Li X, Yu X, et al. Diagnosis of human malignancies using laser-induced breakdown
spectroscopy in combination with chemometric methods[J]. Spectrochimica Acta Part B: Atomic
Spectroscopy, 2018, 139:63-69.
[15] Fang L, Qian X L, Wu B K, et al. Identification method of Xuan paper based on laser-induced
breakdown spectroscopy technique[J]. Chinese Journal of Quantum Electronics,2021,38(03):272-
280(in Chinese).
方莲,钱晓陆,吴本科,丁志鹏,王雅萍.基于激光诱导击穿光谱技术的宣纸鉴别方法研究[J].量
子电子学报,2021,38(03):272-280.
[16] Zeng Q, Pan C Y, Li C Y, et al. Online monitoring of corrosion behavior in molten metal using
laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 2018,
142: 68-73.
[17] Rezaei F, Tavassoli S H. A new method for calculation of thick plasma parameters by
combination of laser spectroscopy and shadowgraphy techniques[J]. Journal of Analytical Atomic
Spectrometry, 2014, 29(12):2371-2378.
[18] Aragón C, Aguilera J A . CSigma graphs: A new approach for plasma characterization in laserinduced
breakdown spectroscopy[J]. Journal of Quantitative Spectroscopy & Radiative Transfer,
2014, 149:90-102.
[19] Yao S, Zhang J, Gao X, et al. The effect of pulse energy on plasma characteristics of
femtosecondfilament assistedablation of soil[J]. Optics Communications, 2018, 425:152-156.
[20] Khalil A, Gnadol M A, Al-Mokbil G. Laser Wavelength and Argon Ambient Gas Pressure
Effects on Metallic Plasma Emission[J]. Journal of Applied Spectroscopy, 2018, 85(4):645-652.
[21] Fikry M, Tawfik W, Omar M M. Investigation on the effects of laser parameters on the plasma
profile of copper using picosecond laser induced plasma spectroscopy[J]. Optical and Quantum
Electronics, 2020, 52(5).
[22] National Institute of Standards and Technology, “NIST Chemistry WebBook, SRD69,”
[Retrieved 28 October 2020], http://webbook.nist.gov/chemistry/form-ser/
[23] Zhang Q H, Liu Y Z, Yin W Y, et al. The in situ detection of smoking in public area by laserinduced breakdown spectroscopy[J]. Chemosphere, 2019, 242:125184.

锌的激光诱导击穿光谱与等离子体温度研究

Investigation of laser⁃induced breakdown spectroscopy and plasma temperature of zinc

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