Analysis of Cu in liquid jet using Double Laser  Induced Breakdown Spectroscopy

Abstract

Abstract: In order to study the heavy metal elements in liquid by double pulse laser induced breakdown spectroscopy, double pulsed laser induced breakdown spectroscopy(DP-LIBS) was used, the LIBS characteristics of Cu elements in a vertical flow of aqueous solution of CuSO4 were measured and analyzed. Two Q-switched Nd:YAG lasers operating at 532nm was utilized to generate plasma on a flowing liquid surface, and plasma signal by detecting the CCD grating spectrometer. The experiment investigated gate delay, the delay time between two lasers of DP-LIBS. The results show that the intensity and SNR of Cu emission lines excited by double pulse is about 2 and 3.3 times than the intensity of line emission excited by the single pulse separately. When the delay time between two lasers at 2~3μs, emission line intensity reached maximum enhancement. The detection limit of metal ion in water solution under the optimized operation conditions was found to be 9.87mg/L for Cu, which is about 6 times than single pulse.

Key words: Spectroscopy, laser induced breakdown spectroscopy, double pulse, liquid jet, limmit of detection

CLC Number:

O436

Hu Zhenhua, Zhang Qiao, Ding Lei, Wang Yingping, Zheng Haiyang, Fang Li. Analysis of Cu in liquid jet using Double Laser Induced Breakdown Spectroscopy[J]. J4, 2014, 31(1): 99-106.

References

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Analysis of Cu in liquid jet using Double Laser Induced Breakdown Spectroscopy

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