Application of variable temperature fluorescence test system with
adjustable pump intensity in quasi-2D perovskite materials

doi:10.3969/j.issn.1007-5461.2021.04.003

Abstract

Abstract: Exciton properties have a decisive influence in the luminescence mechanism of quasi-2D per- ovskite material. Measurement of exciton-phonon coupling strength and exciton binding energy is a pow- erful means of investigating exciton properties of quasi-two-dimensional perovskite materials, which can provide a key scientific basis for revealing the internal light emission mechanism and further improving the fluorescence quantum yield. By combining the adjustable pump intensity fluorescence testing system with the liquid nitrogen thermostat, a set of variable temperature fluorescence test system with adjustable pump intensity is built and controlled by the LABVIEW program. Then the exciton and luminescence properties of quasi two-dimensional perovskite film samples are studied by using the built system. Theexperimental results show that the exciton-longitudinal optical phonon coupling strength and exciton binding energy decrease with the increase of ⟨n⟩-value of quasi-two-dimensional perovskite. In addition, by measuring the adjustable pump intensity fluorescence at room temperature with the built system, the optical gain of quasi-two-dimensional perovskite films is explored, and it is shown that the amplified threshold of spontaneous emission of the film is 3.2 µJ/cm2.

Key words: spectroscopy, exciton properties, variable temperature fluorescence, quasi-2D perovskite; amplified spontaneous emission

CLC Number:

O433.1

ZHANG Bo, GUO Xiuwen, CUI Minghuan, SUN Mingze, LI Gaoqiang, ZHOU Jing, QIN Chaochao∗. Application of variable temperature fluorescence test system with adjustable pump intensity in quasi-2D perovskite materials[J]. Chinese Journal of Quantum Electronics, 2021, 38(4): 420-427.

References

[1]Li Z C, Chen Z M, Yang Y C, et al.Modulation of recombination zone position for quasi-two-dimensional blue perovskite light-emitting diodes with efficiency exceeding 5%[J]. Nature Communications, 2019, 10：1027.[J].Nature Communications, 2019, 10(无):1027-1-1027-6 [2]Jiang Y Z, Qin C C, Cui M H, et al.Spectra stable blue perovskite light-emitting diodes[J]. Nature Communications, 2019, 10：1868.[J].Nature Communications, 2019, 10(无):1868-1-1868-6 [3]Yang X L, Zhang X W, Deng J X, et al.Efficient green light-emitting diodes based on quasi-two-dimensional composition and phase engineered perovskite with surface passivation (vol 9, 2018)[J]. Nature Communications, 2018, 9：570.[J].Nature Communications, 2018, 9(无):570-2-570-6 [4]Qin C J, Matsushima T, Potscavage W J, et al.Triplet management for efficient perovskite light-emitting diodes[J].Nature Photonics, 2020, 14(2):70-75 [5]Wang N N, Cheng L, Ge R, et al.Perovskite light-emitting diodes based on solution-processed self-organized multiple quantum wells[J].Nature Photonics, 2016, 10(11):699-704 [6]Liu Y, Cui J Y, Du K, et al.Efficient blue light-emitting diodes based on quantum-confined bromide perovskite nanostructures[J].Nature Photonics, 2019, 13(11):760-764 [7]Yuan M J, Quan L N, Comin R, et al.Perovskite energy funnels for efficient light-emitting diodes[J].Nature Nanotechnology, 2016, 11(10):872-1-872-6 [8]Shang Q Y, Wang Y N, Zhong Y G, et al.Unveiling Structurally Engineered Carrier Dynamics in Hybrid Quasi-Two-Dimensional Perovskite Thin Films toward Controllable Emission[J].Journal of Physical Chemistry Letters, 2017, 8(18):4431-4438 [9]Leng K, Abdelwahab I, Verzhbitskiy I, et al.Molecularly thin two-dimensional hybrid perovskites with tunable optoelectronic properties due to reversible surface relaxation[J].Nature Materials, 2018, 17(10):908-917 [10]Song J Z, Xu L M, Li J H, et al.Monolayer and Few-Layer All-Inorganic Perovskites as a New Family of Two-Dimensional Semiconductors for Printable Optoelectronic Devices[J].Advanced Materials, 2016, 28(24):4861-4869 [11]Stoumpos C C, Cao D H, Clark D J, et al.Ruddlesden-Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors[J].Chemistry of Materials, 2016, 28(8):2852-2867 [12]Liu J X, Leng J, Wu K F, et al.Observation of Internal Photoinduced Electron and Hole Separation in Hybrid Two-Dimentional Perovskite Films[J].Journal of the American Chemical Society, 2017, 139(4):1432-1435 [13]Xing G C, Wu B, Wu X Y, et al.Transcending the slow bimolecular recombination in lead-halide perovskites for electroluminescence[J]. Nature Communications, 2017, 8：14558.[J].Nature Communications, 2017, 8(无):14558-3-14558-7 [14]Deng S B, Shi E Z, Yuan L, et al.Long-range exciton transport and slow annihilation in two-dimensional hybrid perovskites[J].Nature Communications, 2020, 11(1):664-3-664-8 [15]Liang Y, Shang Q Y, Wei Q, et al.Lasing from Mechanically Exfoliated 2D Homologous Ruddlesden-Popper Perovskite Engineered by Inorganic Layer Thickness[J].Advanced Materials, 2019, 31(39):1903030-1-1903030-5 [16]Bi X M, Liu B, Mcdonald L, et al.Excited-State Intramolecular Proton Transfer (ESIPT) of Fluorescent Flavonoid Dyes: A Close Look by Low Temperature Fluorescence[J].Journal of Physical Chemistry B, 2017, 121(19):4981-4986 [17]Ariese F, Van Assema S, Gooijer C, et al.Comparison of Laurentian Fulvic Acid luminescence with that of the hydroquinonequinone model system: Evidence from low temperature fluorescence studies and EPR spectroscopy[J].Aquatic Sciences, 2004, 66(1):86-94 [18]Hu Y, Moran B M, Woehl J C.Development of a confocal scanning microscope for fluorescence imaging and spectroscopy at variable temperatures[J].Review of Scientific Instruments, 2019, 90(4):043702-2-043702-7 [19]Zhang Y R, Wang L J, Liu P, et al.Measurement and extrapolation modeling of PAH laser-induced fluorescence spectra at elevated temperatures[J].Applied Physics B-Lasers and Optics, 2019, 125(1):6-1-6-3 [20]Jing L, Wenqing L, Nanjing Z, et al.Phytoplankton Chlorophyll Fluorescence Characteristics Excited by Various Light Qualities and Intensities[J].Acta Optica Sinica, 2013, 33(9):0930001-3-0930001-6 [21]Ban M Y, Zou Y T, Rivett J P H, et al.Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nanostructure tailoring[J].Nature Communications, 2018, 9(2):3892-1-3892-5 [22]Pan H, Zhao X J, Gong X, et al.Atomic-Scale Tailoring of Organic Cation of Layered Ruddlesden-Popper Perovskite Compounds[J].Journal of Physical Chemistry Letters, 2019, 10(8):1813-1819 [23]Thirumal K, Chong W K, Xie W, et al.Morphology-Independent Stable White-Light Emission from Self-Assembled Two-Dimensional Perovskites Driven by Strong Exciton-Phonon Coupling to the Organic Framework[J].Chemistry of Materials, 2017, 29(9):3947-3953 [24]Lorke M, Nielsen T R, Seebeck J, et al.Influence of carrier-carrier and carrier-phonon correlations on optical absorption and gain in quantum-dot systems[J].Physical Review B, 2006, 73(8):085324-4-085324-6 [25]Handa T, Aharen T, Wakamiya A, et al.Radiative recombination and electron-phonon coupling in lead-free CH3NH3SnI3 perovskite thin films[J].Physical Review Materials, 2018, 2(7):075402-3-075402-6 [26]Gauthron K, Lauret J S, Doyennette L, et al.Optical spectroscopy of two-dimensional layered (C6H5C2H4-NH3)(2)-PbI4 perovskite[J].Optics Express, 2010, 18(6):5912-5919 [27]Gelvez-Rueda M C, Cao D H, Patwardhan S, et al.Effect of Cation Rotation on Charge Dynamics in Hybrid Lead Halide Perovskites[J].Journal of Physical Chemistry C, 2016, 120(30):16577-16585 [28]Gong X W, Voznyy O, Jain A, et al.Electron-phonon interaction in efficient perovskite blue emitters[J].Nature Materials, 2018, 17(6):550-556 [29]Smith M D, Karunadasa H I.White-Light Emission from Layered Halide Perovskites[J].Accounts of Chemical Research, 2018, 51(3):619-627 [30]Wu K W, Bera A, Ma C, et al.Temperature-dependent excitonic photoluminescence of hybrid organometal halide perovskite films[J].Physical Chemistry Chemical Physics, 2014, 16(41):22476-22481 [31]Mcguire J A, Jin J, Pietryga J M, et al.New aspects of carrier multiplication in semiconductor nanocrystals[J].Accounts of Chemical Research, 2008, 41(12):1810-1819 [32]Milot R L, Sutton R J, Eperon G E, et al.Charge-Carrier Dynamics in 2D Hybrid Metal-Halide Perovskites[J].Nano Letters, 2016, 16(11):7001-7007 [33]Li M L, Gao Q G, Liu P, et al.Amplified Spontaneous Emission Based on 2D Ruddlesden-Popper Perovskites[J].Advanced Functional Materials, 2018, 28(17):1707006-3-1707006-6 [34]Protesescu L, Yakunin S, Bodnarchuk M I, et al.Monodisperse Formamidinium Lead Bromide Nanocrystals with Bright and Stable Green Photoluminescence[J].Journal of the American Chemical Society, 2016, 138(43):14202-14205 [35]Yakunin S, Protesescu L, Krieg F, et al.Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites[J]. Nature Communications, 2015, 6：8056.[J].Nature Communications, 2015, 6(无):8056-3-8056-5 [36]Xing G C, Mathews N, Lim S S, et al.Low-temperature solution-processed wavelength-tunable perovskites for lasing[J].Nature Materials, 2014, 13(5):476-480 [37]Sutherland B R, Hoogland S, Adachi M M, et al.Conformal Organohalide Perovskites Enable Lasing on Spherical Resonators[J].Acs Nano, 2014, 8(10):10947-10952 [38]Yakunin S, Protesescu L, Krieg F, et al.Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites (vol 6, 8056, 2015)[J]. Nature Communications, 2015, 6：9056.[J].Nature Communications, 2015, 6(无):9056-1-9056-4

Application of variable temperature fluorescence test system with adjustable pump intensity in quasi-2D perovskite materials

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