Tb3+-Yb3+离子对的近红外量子剪裁进展研究

J4 ›› 2014, Vol. 31 ›› Issue (4): 466-471.

• 《量子电子学报》创刊三十周年纪念专辑 • 上一篇下一篇

Tb3+-Yb3+离子对的近红外量子剪裁进展研究

杨晓冬，陈晓波，陈栾，周固，冯倩，王水锋，刘洁，李崧，刘金英，周禹声，王亚非，程欢利

北京师范大学物理学系与应用光学北京重点实验室，北京， 100875

出版日期:2014-07-28 发布日期:2014-07-30
通讯作者: 陈晓波（1962-），福州人，博士，教授，博士生导师，研究方向为光物理，稀土材料发光光谱。 E-mail:chen78xb@sina.com
作者简介:杨晓冬（1989-），女，河南人，博士生。研究方向为光物理，稀土材料发光光谱。Email:hzsdyxd@163.com

Progress in near-infrared quantum cutting of Tb3+-Yb3+ ion pair

YANG Xiao-dong, CHEN Xiao-bo，CHEN Luan，Zhou Gu，FENG Qian，WANG Shui-feng，LIU Jie，LI Song，LIU Jin-ying，ZHOU Yu-sheng，WANG Ya-fei，CHENG Huan-li

Department of Physics, Beijing Normal University, Beijing Key Laboratory of Applied Optics，Beijing, 100875, China

Published:2014-07-28 Online:2014-07-30

摘要/Abstract

摘要： 近红外量子剪裁能够有效地提高硅太阳能电池的效率。稀土元素种类繁多，能级丰富，常被用于制作近红外量子剪裁发光材料。研究者们用适当的方法制成发光材料之后，测量材料的吸收光谱，激发光谱和发射光谱。根据这些数据计算得到材料的量子效率。其中Tb3+-Yb3+离子对备受关注。Tb3+吸收紫外-可见光，通过协同能量传递把能量传递给Yb3+离子。Yb3+离子跃迁辐射出1000nm左右的近红外光。该波段的光子能够被硅太阳能电池吸收利用。Tb3+-Yb3+离子对在不同掺杂浓度，不同基质中得到的量子效率不同。

关键词: 光谱学；近红外量子剪裁；能量传递；Tb3+-Yb3+离子对

Abstract: Near-infrared quantum cutting is a promising approach to enhance the efficiency of silicon solar cells. There are many different kinds of rare earth elements, and each of them has abundant energy levels. Researchers prepare luminescent materials doped with rare earth elements; measure the absorption spectra, the excitation spectra and emission spectra of the materials. According to these data, they calculate the quantum efficiency of luminescent materials. The Tb3+-Yb3+ ions have been drawing people’s attention. Upon excitation of Tb3+ ion with a ultraviolet-visible photon, Yb3+ ion can emit two near-infrared photons around 1000 nm through cooperative energy transfer from Tb3+ ion to Yb3+ ion. The near-infrared photons can be absorbed by silicon solar cells. The quantum efficiency varies from concentration of Tb3+/Yb3+ ions as well as the matrix of material.

Key words: spectroscopy；near-infrared quantum cutting；Tb3+-Yb3+ ions；energy transfer

中图分类号:

TN2
O482.3

杨晓冬，陈晓波，陈栾，周固，冯倩，王水锋，刘洁，李崧，刘金英，周禹声，王亚非，程欢利. Tb3+-Yb3+离子对的近红外量子剪裁进展研究[J]. J4, 2014, 31(4): 466-471.

YANG Xiao-dong, CHEN Xiao-bo，CHEN Luan，Zhou Gu，FENG Qian，WANG Shui-feng，LIU Jie，LI Song，LIU Jin-ying，ZHOU Yu-sheng，WANG Ya-fei，CHENG Huan-li. Progress in near-infrared quantum cutting of Tb3+-Yb3+ ion pair[J]. J4, 2014, 31(4): 466-471.

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Tb3+-Yb3+离子对的近红外量子剪裁进展研究

Progress in near-infrared quantum cutting of Tb3+-Yb3+ ion pair

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